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Villarreal vs Napoli Prediction and Betting Tips

Villarreal welcome Napoli to Estadio de la Cerámica in Villarreal in UEFA Champions League action on Wednesday 14 October 2026.

Villarreal have played 7 matches in UEFA Champions League this season, scoring 1.9 and conceding 1.7 goals a game and winning 29% of them. At home they average 2.0 goals scored and 2.0 conceded over 3 matches, with a 50% win rate. Napoli have played 5 matches in UEFA Champions League this season, scoring 1.4 and conceding 1.2 goals a game and winning 40% of them. Away from home they average 1.7 goals scored and 1.3 conceded over 3 matches, with a 50% win rate.

On the bookmakers' prices, with their margin taken out, there is little to separate them: Villarreal 41%, the draw 27%, Napoli 31%.

The odds

Villarreal2.1941%
Draw3.3527%
Napoli2.8931%

Decimal odds; the percentages are the chances the prices imply once the bookmaker's margin (10.1% on this market) is taken out. The main Asian handicap is Villarreal -0.25 at 1.98, Napoli at 1.90. The main goals line is 2.75: over 1.93, under 1.94, which gives over 50%.

Villarreal: form and key numbers

In style Villarreal keep the ball, press high, take players on.

Napoli: form and key numbers

Villarreal vs Napoli: season averages side by side

VillarrealPer matchNapoli
2.28Expected goals (xG)1.48
1.34xG conceded1.59
1.86Goals1.40
16.0Shots13.8
6.6Shots on target4.2
2.4Big chances missed2.0
69.1Pressure share %51.5
14.9Tackles17.0
10.7Fouls9.6
2.0Yellow cards0.8

Season averages per match from Sportmonks, over 7 and 5 measured matches.

Villarreal vs Napoli: head-to-head stats and key numbers

Head to head

In their last 6 meetings Villarreal won 2, drew 2 and lost 2.

DateHomeScoreAway
25 Feb 2016Napoli1 – 1Villarreal
18 Feb 2016Villarreal1 – 0Napoli
7 Dec 2011Villarreal0 – 2Napoli
27 Sep 2011Napoli2 – 0Villarreal
24 Feb 2011Villarreal2 – 1Napoli
17 Feb 2011Napoli0 – 0Villarreal

Players to watch

Villarreal

Napoli

Scouting spotlight: Alberto Moleiro

Alberto Moleiro, 23 · Villarreal · LWF · Creative winger · Moneyball Score 72

Alberto Moleiro, 23, plays as a winger for Villarreal in La Liga. Strongest for his role in expected assists (est.) and key passes. Weakest in fouls won. Moneyball Scout, the engine behind our Scouting Players Research, rates him against every winger in Europe's top five leagues - and this is what he does better than almost all of them.

Successful dribbles 42Expected goals 81Expected assists 98Key passes 98Shots 52Accurate crosses 84Big chances created 94Fouls won 22Dispossessed 44

Percentile against his position on each figure: 50 is the average winger, 90 the top tenth.

Positions he can play

  • LW · Winger Natural, 72
  • RW · Winger Accomplished, 68
  • CAM · Attacking midfielder Competent, 62

Where he is strongest

FigureHis numberBetter than
Expected assists (est.)0.47 / 9098%
Key passes3.50 / 9098%
Big chances created0.88 / 9094%
Accurate crosses1.53 / 9084%
Expected goals0.33 / 9081%

Roles he suits

  • ★★★★★ Creative winger Winger
  • ★★★★½ Wide playmaker Wide midfielder
  • ★★★½ Classic winger Winger

Scout's notes: Creator, Chance creator, Big-chance creator.

In Moneyball Scout
  • What Alberto Moleiro is worth on the market, and the most a club should pay
  • How many league points he would add to your club (Win-Rate Impact)
  • The players who play like him, cheaper - the Replacement Finder
  • His chemistry with your squad, his fit with your style, his projection by age

Open Alberto Moleiro's full file Moneyball Scout from $39 a month

Villarreal vs Napoli prediction

Villarreal should have more of the ball, with Napoli likely to sit in a compact block and look to break; Villarreal like to take players on. Moneyball's model expects about 3.4 goals - 2.03 for Villarreal and 1.38 for Napoli - with over 2.5 goals at 66% and both teams scoring at 65%. Little separates the sides on the numbers, and a draw is the single likeliest result.

Prediction: Villarreal 1-1 Napoli

The full model, every line of this match, in the Match Centre

Villarreal vs Napoli betting tips

  1. Tip 1: Draw or either side by one goal is the shape of it - avoid the result market no side above 41%
  2. Tip 2: Over 2.5 goals 66% by the model, 3.40 goals expected
  3. Tip 3: Both teams to score: yes 65% by the model
  4. Tip 4: Under 4.5 cards the two sides average 2.8 cards a match between them
  5. Tip 5: Over 9.5 corners 12.7 corners a match between them

Statistical leanings from the data, not certainties. 18+ only, where betting is legal; never stake more than you can afford to lose.

Moneyball's pick

The Dixon-Coles and xG model prices every line of this match: the win, draw and loss probabilities, fair odds and the expected value of each handicap and goals line. The full analysis of this match is part of Moneyball Premium.

Open Villarreal vs Napoli in the Match Centre Follow it live

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Villarreal vs Napoli: questions and answers

When is Villarreal vs Napoli?

Villarreal vs Napoli is on Wednesday 14 October 2026, in UEFA Champions League.

Where is Villarreal vs Napoli played?

At Estadio de la Cerámica, Villarreal, Villarreal's home ground.

Who will win Villarreal vs Napoli?

It is close: Villarreal 41%, draw 27%, Napoli 31%. Our prediction is Villarreal 1-1 Napoli.

Who is the player to watch in Villarreal vs Napoli?

Alberto Moleiro of Villarreal: a creative winger with a Moneyball Score of 72 against every winger in Europe's top five leagues.

How many goals will there be in Villarreal vs Napoli?

Moneyball's model expects about 3.4 goals, with over 2.5 goals at 66%.

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Moneyball Odds is a statistical analysis site, not a bookmaker. No model predicts football reliably. For readers aged 18 and over, where betting is legal.